Product Name: Lithium Naphthenate
Chemical Formula: Not standardized, contains lithium salts of naphthenic acids
Synonyms: Lithium Naphthenate Solution, Lithium naphthenic acid
Recommended Uses: Drying agent in paints and coatings, catalyst in chemical synthesis, lubricant additive
Manufacturer: Refer to sourcing supplier for detailed contact information
Emergency Telephone: Refer to local Poison Control Center or fire department
Product Description: Liquid containing dissolved lithium naphthenate in hydrocarbon solvent
Relevant Identifiers: CAS numbers for lithium salts and naphthenic acid mixtures vary by manufacturer batch
Intended Sector of Use: Industrial processes, laboratory applications
Emergency Overview: Clear to dark brown liquid with mild petroleum odor
GHS Classification: Flammable liquid, Category 3; Acute toxicity, Category 4 (oral, dermal, inhalation); Eye and skin irritant
Hazard Symbols: Flame, Exclamation mark
Signal Word: Warning
Hazard Statements: Flammable liquid and vapor; Harmful if inhaled, swallowed, or absorbed through skin; Causes skin and eye irritation; May affect the central nervous system
Precautionary Statements: Avoid breathing vapor or mist; Wear protective clothing; Use only in well-ventilated areas; Keep away from heat/sparks/open flames; Wash thoroughly after handling
Potential Health Effects: Shortness of breath, headache, nausea, dizziness, skin reddening, possible sensitization
Main Component: Lithium naphthenate (lithium salt of naphthenic acid), concentration range 10-30% w/w
Solvent: Hydrocarbon carrier (often light mineral oil or naphtha), 70-90% w/w
Impurities: Possible low levels of naphthenic acid, lithium hydroxide, and residual oils
CAS Numbers: Naphthenic acids (1338-24-5); Specific CAS for lithium salt not generally established
Other Constituents: Trace stabilizers or corrosion inhibitors may be present depending on manufacturer
Inhalation: Remove person to fresh air; seek medical attention for persistent symptoms such as coughing, dizziness, or headache
Skin Contact: Immediately wash exposed skin thoroughly with soap and water; remove contaminated clothing; obtain medical advice if irritation persists
Eye Contact: Rinse cautiously with water for at least 15 minutes while lifting lids; contact medical professional if irritation develops
Ingestion: Rinse mouth with water; do not induce vomiting; get immediate medical attention
Notes to Physician: Treat symptomatically; monitor for chemical pneumonitis if large quantities inhaled
Extinguishing Media: Use foam, carbon dioxide, dry chemical; water spray may be used to cool containers
Unsuitable Media: Avoid direct streams of water which may spread fire
Specific Fire Hazards: Vapors may form explosive mixtures with air; product combusts and produces toxic fumes including metal oxides and carbon monoxide
Protective Equipment: Self-contained breathing apparatus and full protective gear recommended for firefighters
Special Methods: Dike area to prevent runoff into drains and waterways; cool fire-exposed containers
Personal Precautions: Evacuate area, ventilate, eliminate ignition sources, prevent inhalation and skin contact
Environmental Precautions: Prevent from entering surface water, sewers, or soil; notify authorities if large quantities released
Containment: Stop leak safely, dike spill with inert materials such as sand or earth
Cleanup Methods: Absorb with inert material, then collect using non-sparking tools; dispose according to regulatory requirements
Additional Advice: Wear gloves, chemical splash goggles, and suitable respiratory protection during cleanup
Handling: Use in well-ventilated areas; keep containers tightly closed; avoid contact with skin, eyes, and clothing; ground all equipment to prevent static; keep away from open flames and sparks
Storage: Store in cool, dry, well-ventilated storage away from sunlight, oxidizers, and incompatible materials such as acids and halogens; keep in original container
Hygiene Measures: Wash hands and face thoroughly after handling; no eating, drinking, or smoking in work area
Incompatibilities: Acids, strong oxidizers, and moisture can cause hazardous reactions
Occupational Exposure Limits: No established limits specifically for lithium naphthenate; observe limits for solvent component (typically 100 ppm for naphtha)
Engineering Controls: Ensure effective local exhaust ventilation
Personal Protective Equipment: Chemical-resistant gloves (nitrile, neoprene), safety goggles or face shield, flame-resistant clothing or lab coat
Respiratory Protection: Chemical cartridge respirator if ventilation inadequate or levels exceed occupational exposure limits
Environmental Protection: Use closed systems and local ventilation to avoid emissions; capture spills and prevent release
Physical State: Liquid
Color: Pale to dark brown
Odor: Mild hydrocarbon/petroleum
Boiling Point: Typically between 140-200°C, varies by solvent
Density: 0.85-0.95 g/cm³
pH: Not applicable (non-aqueous system)
Vapor Pressure: 2-15 mmHg at 20°C (solvent dependent)
Viscosity: Medium to low
Flash Point: 35-60°C, flammable in presence of ignition source
Solubility: Not soluble in water; soluble in nonpolar solvents
Chemical Stability: Stable under normal storage conditions
Reactivity: Can react with acids, bases, strong oxidizing agents; moisture promotes hydrolysis
Hazardous Decomposition: Releases lithium oxide, carbon oxides, irritating organic vapors on burning
Polymerization: Does not polymerize
Conditions to Avoid: Heat, open flame, spark, direct sunlight, moisture
Acute Toxicity: Harmful by inhalation, ingestion, or skin absorption; estimated LD50 values for similar compounds range 200-2000 mg/kg (oral, rat)
Irritation: Causes moderate skin and eye irritation
Sensitization: May cause allergic skin reaction in sensitive individuals
Chronic Effects: Prolonged or repeated exposure can cause dermatitis, central nervous system depression, liver and kidney effects
Specific Effects: Some naphthenates reported to cause respiratory tract irritation and central nervous system symptoms
Carcinogenicity: Not classified as carcinogenic by IARC, NTP, or OSHA
Ecotoxicity: Toxic to aquatic organisms including fish, daphnia, and algae; estimated aquatic LC50 < 10 mg/L
Mobility: Product floats on water; hydrocarbon solvent evaporates readily
Persistence and Degradability: Naphthenic acids degrade slowly; persistence in soil or sediments possible
Bioaccumulation: Possible moderate bioaccumulation potential in aquatic environments
Other Adverse Effects: Lithium compounds at high concentrations may be toxic to plants and aquatic life
Waste Disposal Methods: Incinerate or dispose of at facility authorized to handle hazardous waste; do not pour into drains, soil, or waterways
Container Disposal: Triple rinse, puncture, and send to approved drum reconditioner or incinerator
Regulatory Controls: Follow local, state, and federal regulations for hazardous waste disposal
Precautions: Use protective equipment and avoid direct exposure during waste transfer
UN Number: 1993 (for flammable liquid, n.o.s. containing naphtha base)
Proper Shipping Name: Flammable liquid, n.o.s. (contains lithium naphthenate, petroleum solvent)
Transport Hazard Class: 3 (flammable liquids)
Packing Group: III
Marine Pollutant: Yes
Labeling Requirements: Flammable liquid diamond, marine pollutant label if applicable
Special Precautions: Keep away from incompatible materials, ensure no leakage during transport, use approved containers
US TSCA Status: All components generally listed or exempt
SARA Title III: Contains chemicals subject to reporting requirements
OSHA Classification: Hazardous chemical as defined by Hazard Communication Standard
WHMIS (Canada): B2 (Flammable liquid), D2B (Toxic material causing other effects)
REACH (EU): Contact local supplier for registration information
Label Elements: Flammable, harmful, eye irritant, aquatic toxicity
Workplace Labeling: Follow all hazard communication requirements in jurisdiction
Additional Regulations: Verify with local authorities for storage and handling permits specific to this material
